低烟无卤阻燃聚烯烃电缆料吸水性与电性能的关系
Relationship Between Moisture Absorption Performance and Electrical Properties of Low Smoke Zero Halogen Flame Retardant Polyolefin Cable Material
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摘要: 为探究低烟无卤阻燃聚烯烃电缆料吸水率对其电性能的影响,通过调整乙烯-乙酸乙烯酯共聚物(ethylene-vinyl acetate copolymer,EVA)与茂金属线性低密度聚乙烯(metallocene linear low-density polyethylene,mLLDPE)的比例调控材料的吸水率,系统测试了不同吸水率下材料的介电常数、介质损耗角正切、浸水电容、体积电阻率及浸水击穿强度,并考察了辐照交联对击穿性能的作用。结果表明:随着吸水率的上升,介电常数、介质损耗角正切和浸水电容均呈先缓后急的增加趋势;浸水击穿强度则先急剧下降,后降幅趋缓。在高湿环境中,辐照交联残留的微裂纹或自由基位点与极性基团结合,加剧了界面极化与离子导电,导致泄漏电流增大、击穿强度持续下降,最终接近未交联水平。在低吸水率条件下,辐照交联形成的三维网络结构可限制分子链运动、减少内部空隙,使击穿强度较高且变化缓慢。该研究为通过吸水率预测电缆料的电气性能及提升其长期可靠性提供了依据。Abstract: To investigate the influence of water absorption rate on electrical properties of low smoke zero halogen flame retardant polyolefin cable material, water absorption rate was regulated by adjusting the ratio of ethylene-vinyl acetate copolymer (EVA) to metallocene linear low-density polyethylene (mLLDPE). Dielectric constant, dielectric loss tangent, immersion capacitance, volume resistivity, and immersion breakdown strength under different water absorption rates were systematically measured, and the effect of irradiation cross-linking on breakdown performance was examined. Results showed that with the increase of water absorption rate, dielectric constant, dielectric loss tangent and immersion capacitance increased gradually first and then sharply, while immersion breakdown strength decreased sharply initially and then more slowly. In a high-humidity environment, possible residual microcracks or free radical sites from irradiation cross-linking combined with polar groups, enhanced interface polarization and ionic conduction, led to a sharp rise in leakage current and a continuous decrease in breakdown strength, eventually approaching the level of non-crosslinked materials. Under conditions of low water absorption rate, three-dimensional network structure formed by irradiation cross-linking restricted molecular chain movement, reduced internal voids, resulting in a higher and more slowly varying breakdown strength. The study could provide a reference for predicting electrical properties of cable materials based on water absorption rate and improving their long-term reliability.
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