基于主成分分析的氯化聚乙烯护套料低温性能快速评价方法
Rapid Evaluation Method of Low-Temperature Performance for Chlorinated Polyethylene Sheathing Materials Based on Principal Component Analysis
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摘要: 针对氯化聚乙烯电缆护套料低温性能评价方法的局限性,提出一种基于主成分分析的多尺度联用快速评价体系。通过整合脆性温度(brittleness temperature,Tb)、低温回缩温度(temperature retraction,TR)、动态热机械分析玻璃化转变温度(glass transition temperature by dynamic mechanical analysis,TgDMA)及低温拉伸断裂伸长率(elongation at break in low temperature,Eb)等数据,发现在Tb、TgDMA及Eb的组合中,第1主成分(PC1)的贡献率为61.32%,PC1得分与低温扭转试验结果负相关(r=−0.83);在Tb、回缩率为10%时的低温回缩温度(TR10)及Eb的组合中,PC1的贡献率为48.65%,PC1得分与低温扭转试验结果正相关(r=0.63)。结果表明,该评价体系将测试周期缩短50%以上,数据解释能力提升30%。尽管样本量较小(n=11),结论还需通过更大规模数据的验证,但提出了一种基于主成分分析的多尺度联用低温性能评价框架,为材料的快速筛选或配方与工艺的优化提供了新方法。Abstract: To address limitations of existing evaluation methods for the low-temperature performance of chlorinated polyethylene cable sheathing materials, a rapid multi-scale evaluation system based on principal component analysis (PCA) was proposed. By integrating data from brittleness temperature (Tb), temperature retraction (TR), glass transition temperature by dynamic mechanical analysis (TgDMA), and elongation at break in low temperature (Eb), the following findings were obtained. In the combination of Tb, TgDMA and Eb, contribution rate of PC1 could reach 61.32%, with PC1 scores exhibiting a negative correlation with low-temperature torsion test results (r=−0.83). While, in the combination of Tb, temperature retraction at 10% (TR10) and Eb, contribution rate of PC1 was 48.65%, and PC1 scores showed a positive correlation with low-temperature torsion test results (r=0.63); Results showed that the model could reduce testing time by over 50% and improve data interpretability by 30%. Although the limited sample size (n=11) necessitated validation with larger datasets, the proposed multi-scale evaluation framework for low-temperature performance based on PCA could provide an innovative methodological reference for rapid material screening or optimization of formulations and processing techniques.
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