低烟无卤阻燃聚烯烃绝缘料的耐水性能
Water Resistance of Low-Smoke Halogen-Free Flame Retardant Polyolefin Insulation
-
摘要: 针对低烟无卤阻燃聚烯烃绝缘料吸湿性强,严重影响低烟无卤电缆长期运行的稳定性和安全性问题,通过重量法研究不同品种树脂、不同品种阻燃剂、辐照交联对绝缘料耐水性能的影响。结果表明:绝缘料吸水率随着乙烯-乙酸乙烯共聚物(EVA)含量的下降而下降,随着茂金属线型低密度聚乙烯(mLLDPE)和乙烯-辛烯共聚物(POE)含量的增加而下降;氢氧化镁(MDH)原粉的吸水率明显高于氢氧化铝(ATH)原粉,碳酸钙(CaCO3)原粉最低;改性后无机阻燃剂的吸水率较低;随着辐照剂量的逐渐增加,交联度增大,绝缘料吸水率下降。以上研究成果可为电缆料选型提供参考意见,特别是对湿度有要求的低烟无卤阻燃绝缘料。Abstract: Due to the strong hygroscopicity of low-smoke halogen-free flame retardant polyolefin insulation, which seriously affects the long-term operational stability and safety of low-smoke halogen-free cable, influence of different types of resins, various flame retardants and irradiation cross-linking on water resistance of insulation materials was investigated using the gravimetric method. Results indicated that water absorption rate of the insulation material decreased as the content of ethylene vinyl acetate copolymer (EVA) decreased, and it also decreased with the increase in the proportion of metallocene linear low-density polyethylene (mLLDPE) and poly (ethylene-co-1-octene) (POE). Among flame retardants, magnesium hydroxide (MDH) raw powder exhibited a significantly higher water absorption rate than aluminum hydroxide (ATH) raw powder, whereas calcium carbonate (CaCO3) raw powder demonstrated the lowest. Additionally, modified inorganic flame retardants showed a lower water absorption rate. Furthermore, as the irradiation dose gradually increased, the degree of cross-linking rose, leading to a progressive reduction in water absorption rate of the insulation material. The above research results could provide reference for the selection of cable materials, especially low-smoke halogen-free flame retardant insulating materials with humidity requirements.
©上海电缆研究所有限公司《电线电缆》编辑部版权所有,未经授权不得转载、改编。