纳米海泡石对镁磷体系阻燃EVA的影响
Effect of Mano Sepiolite on Flame Retardant EVA in Magnesium Phosphorus System
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摘要: 本文以纳米海泡石作为增效剂制备了阻燃乙烯-醋酸乙烯共聚物(EVA)复合材料。根据材料配方制备样品,并通过硬度、拉伸试验、热失重分析、氧指数和锥形热量计测试等,分析纳米海泡石对镁磷体系阻燃EVA的机械性能、热性能和阻燃性能的影响。结果表明,随着纳米海泡石添加量的增加,样品硬度呈上升趋势,断裂强度呈下降趋势,断裂伸长率呈先上升后下降的趋势。绝缘电阻方面,纳米海泡石的添加量小于2 g时,样品体积电阻率提高,而纳米海泡石的添加量超过2 g时样品体积电阻率却急剧下滑。热性能方面,随着纳米海泡石添加量的增加,样品的初始熔融温度、熔融峰、结晶温度和结晶度等均先升高后降低;受热过程有3个失重阶段,第一分解峰温度在纳米海泡石添加量小于2 g时,变化较小;纳米海泡石添加量大于2 g时,下降幅度较大;随着海泡石添加量的增加第二分解峰温度从383.8 ℃下降至375.9 ℃,第三分解峰温度基本保持不变。极限氧指数测试结果表明,随着纳米海泡石添加量的增加,极限氧指数逐渐上升,从32.7%上升至34.7%。锥形量热试验结果表明,适量添加纳米海泡石可有效降低火灾行为参数。灰烬图片表明纳米海泡石添加量为2 g时能与阻燃剂形成致密的结壳层,起到阻碍火苗向内部扩散的作用。Abstract: Nano sepiolite was used as a synergist to prepare flame-retardant ethylene vinyl acetate copolymer (EVA) composite materials. Influence of nano sepiolite on the mechanical, thermal, and flame retardant properties of magnesium phosphorus flame retardant EVA was studied through hardness, tensile testing, thermogravimetric analysis (TGA), oxygen index (LOI), and cone calorimeter testing. Hardness test results indicated that as the content of sepiolite increases, hardness showed an upward trend. Tensile performance results showed that with the increase of sepiolite content, tensile strength decreased, and the elongation first increased and then decreased. Volume resistivity test results showed that with the addition of nano sepiolite, the volume resistivity of composite material increased, while when the amount of nano sepiolite added was less than 2 g, the volume resistivity of EVA composite material sharply decreased.In terms of thermal performance, as the amount of nano sepiolite added increased, the initial melting temperature, melting peak, crystallization temperature, and crystallinity of the sample first increased and then decreased;There were three stages of weight loss during the heating process, and the temperature of the first decomposition peak changed slightly when the amount of nano sepiolite added was less than 2 g; When the amount of nano sepiolite added was greater than 2 g, the decrease was significant; As the amount of sepiolite added increases, the temperature of the second decomposition peak decreased from 383.8 ℃ to 375.9 ℃, while the temperature of the third decomposition peak remained basically unchanged. The results of the Limiting Oxygen Index (LOI) test showed that with the amount of sepiolite added, the LOI gradually increased, rising from 32.7% to 34.7%. The results of the cone calorimeter test indicated that an appropriate amount of nano sepiolite can effectively reduce fire behavior parameters, such as heat release rate (HRR), total heat (THR), total smoke release (TSP), and mass loss rate (MLR). The photos of ashes indicated that when the amount of sepiolite added was 2 g can form a dense crust layer with flame retardants, thereby hindering the spread of flames inward.
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